Product ID:SEMI-VOLATILE SPIKING MIXTURE (TCLP), TCLP-BNA
MSDS Date:07/21/1994
FSC:6630
NIIN:00N071363
MSDS Number: CBNRB

ACCUSTANDARD INC

25 SCIENCE PARK SUITE 687
NEW HAVEN, CT 06511
US

Emergency Phone: 203-786-5290

Info Phone: 203-786-5290

Cage: 0U4A8

ACCUSTANDARD INC

NEW HAVEN, CT 06513 US

Telephone: 800-442-5290

Cage: 0U4A8

O-CRESOL; (2-METHYLPHENOL) (SARA 302/313) (CERCLA)

CAS: 95-48-7

RTECS: GO6300000

Fraction By Weight: 0.2%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-CRESOL; (3-METHYLPHENOL) (SARA 313) (CERCLA)

CAS: 108-39-4

RTECS: GO6125000

Fraction By Weight: 0.2%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-CRESOL; (4-METHYLPHENOL)

CAS: 106-44-5

RTECS: GO6475000

Fraction By Weight: 0.2%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 5 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.2%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM, A3; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TOLUENE, 2,4-DINITRO-; (2,4-DINITROTOLUENE) (SARA 313)

CAS: 121-14-2

RTECS: XT1575000

Fraction By Weight: 0.2%

OSHA PEL S, 1.5 MG/M3

ACGIH TLV: 0.15 MG/M3, A2; 9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

BENZENE, HEXACHLORO-; (HEXACHLOROBENZENE) (SARA 313)

CAS: 118-74-1

RTECS: DA2975000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,3-BUTADIENE, HEXACHLORO-; (HEXACHLOROBUTADIENE) (SARA

CAS: 87-68-3

RTECS: EJ0700000

Fraction By Weight: 0.2%

OSHA PEL 0.02 PPM

ACGIH TLV: S,0.02 PPM, A2; 9495

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHANE, HEXACHLORO-; (HEXACHLOROETHANE) (SARA 313) (CERCLA)

CAS: 67-72-1

RTECS: KI4025000

Fraction By Weight: 0.2%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM, A2; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, NITRO-; (NITROBENZENE) (SARA 302/313)

CAS: 98-95-3

RTECS: DA6475000

Fraction By Weight: 0.2%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHENOL, PENTACHLORO-; (PENTACHLOROPHENOL) (SARA 313)

CAS: 87-86-5

RTECS: SM6300000

Fraction By Weight: 0.2%

OSHA PEL S, 0.5 MG/M3

ACGIH TLV: S, 0.5 MG/M3; 9495

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PYRIDINE (SARA 313) (CERCLA)

CAS: 110-86-1

RTECS: UR8400000

Fraction By Weight: 0.2%

OSHA PEL 5 PPM

ACGIH TLV: 5 PPM; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHENOL, 2,4,5-TRICHLORO-; (2,4,5-TRICHLOROPHENOL) (SARA

CAS: 95-95-4

RTECS: SN1400000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL, 2,4,6-TRICHLORO-; (2,4,6-TRICHLOROPHENOL) (SARA

CAS: 88-06-2

RTECS: SN1675000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 97.4%

OSHA PEL 500 PPM; Z-2

ACGIH TLV: 50 PPM, A2; 9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ANTIC TO BE CARCIN.

RTECS: 9999999ZZ

ANTIC TO BE CARCIN.

RTECS: 9999999ZZ

GROUP 2B.

RTECS: 9999999ZZ

IARC MONO, SUPP VOL 7, PG

RTECS: 9999999ZZ

ANTICIPATED TO BE CARCINOGEN.

RTECS: 9999999ZZ

MYOCARDIUM TO EPINEPHRINE IN LABORATORY

RTECS: 9999999ZZ

ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE

RTECS: 9999999ZZ

Fraction By Weight: M/K

ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE EYE INJURY. INHALATION OF
HIGH VAPOR CONCENTRATION CAUSES DIZZINESS, NAUSEA, HEADACHE,
NARCOSIS, IRREGULAR HEARTBEATS, COMA AND DEATH. INGESTION MAY CAUSE
IRRITATION OF THE GASTROINTESTINAL TRACT WITH VOMITING. IF
VOMITING OCCURS, METHYLENE CHLORIDE CAN BE ASPIRATED INTO THE
LUNGS, WHICH (EFTS OF OVEREXP)
Explanation of Carcinogenicity:HEXACHLOROBENZENE:IARC MONOGRAPHS,
SUPPLEMENT, VOL 7, PG 219, 1987: GROUP 2B. NTP 7TH ANNUAL REPORT ON
(SUPDAT)
Effects of Overexposure:HLTH HAZ:CAN CAUSE CHEMICAL PNEUMONIA AND
SYSTEMIC EFFECTS. EXCESSIVE EXPOSURE MAY CAUSE BLOOD DEFECTS AND
CAN AFFECT LIVER, KIDNEYS AND CENTRAL NERVOUS SYSTEM. TOXIC BY
INGESTION AND INHALATION. IRRI TATION ON CONTACT WITH SKIN, EYES OR
MUCOUS MEMBRANES. CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE(ING 20)
Medical Cond Aggravated by Exposure:HEART, KIDNEY AND LIVER CONDITIONS.

First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN:
WASH THOROUGHLY WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH
THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE
TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS
STOPPED. INGESTION: DO NOT INDUCE VOMITING; GET IMMED MEDICAL
ATTENTION.

Flash Point:NONE
Lower Limits:13.00%
Upper Limits:23.00%
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FORMS FLAMMABLE VAPOR-AIR MIXTURES ABOVE
AMBIENT TEMPERATURE. THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE .

Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED
UNDER EXPOSE/PERSONAL PROTECTION. ELIMINATE ANY IGNIT SOURCES UNTIL
THE AREA IS DETERMINED TO BE FREE FROM EXPLOSION/FIRE HAZARDS.
CONTAIN THE RELEASE & ELIMI NATE ITS SOURCE, IF THIS CAN BE DONE
WITHOUT RISK.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN A COOL, WELL-VENTILATED AREA AWAY FROM OPEN FLAMES. DO NOT
BREATHE VAPOR OR MIST.
Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT
TAKE INTERNALLY.

Respiratory Protection:IF WORKPLACE EXPOS LIM (S) OF PROD/ANY COMPONENT
IS EXCEEDED (SEE TLV/PEL), A NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA RE SPS (NEGATIVE PRESS TYPE) (SUPDAT)
Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME
HOOD OR WITH EQUIVALENT VENTILATION.
Protective Gloves:VITON, PVA OR EQUIVALENT.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
RESP PROT: UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT
SUPPLIER). ENGINEERING &/ADMINISTRATIVE CTLS SHOULD BE IMPLEMENTED
TO REDUCE EXPOS. EXPLAN OF CARCIN: CARCINOGENS, 1994:ANTIC TO BE
CAR CIN. ANIMAL:KIDNEY, BLOOD, THYROID. P-DICHLOROBENZENE:IARC
MONO, SUPP, VOL 7, PG 292, 1987: GROUP 2B. NTP 7TH (ING 15)

Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:340 @ 20C
Vapor Density:2.93
Spec Gravity:1.326 (H*20=1)
Evaporation Rate & Reference:27.5 (BUAC = 1)
Solubility in Water:2%
Appearance and Odor:COLORLESS LIQUID, ETHER-LIKE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
BASES, OXIDIZERS, ALKALI METALS, ALUMINUM AND MAGNESIUM POWDER, SODIUM,
POTASSIUM AND LITHIUM.
Stability Condition to Avoid:CONTACT WITH OPEN FLAME, WELDING ACRS, HOT
SURFACES.
Hazardous Decomposition Products:HCL, PHOSGENE, CHLORINE

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. COMPLY WITH FEDERAL,
STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.